LBF18303HP04
From Jcbl.jp
| LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
| IDs and Links | |
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| LipidBank | |
| DFA8054 | |
| LipidMaps | |
| LMFA01040038 | |
| CAS | |
| KEGG | |
| {{{KEGG}}} | |
| KNApSAcK | |
| LBF18303HP04.mol | |
| Methyl-10-hydroperoxy- (8E,12Z,15Z) -octadecatrienoic acid | |
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| Structural Information | |
| Systematic Name | Methyl-10-hydroperoxy- (trans-8,cis-12,cis-15) -octadecatrienoic acid |
| Common Name |
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| Symbol | |
| Formula | C19H32O4 |
| Exact Mass | 324.23005951199997 |
| Average Mass | 324.45498 |
| SMILES | CCC=CCC=CCC(OO)C=CCCCCCCC(=O)OC |
| Physicochemical Information | |
| Melting Point | |
| Boiling Point | |
| Density | |
| Optical Rotation | |
| Refractive Index | |
| Solubility | |
| Source | Oxidation of linoleate by singlet oxygen Frankel_EN Frankel_EN Frankel_EN . |
| Chemical Synthesis | |
| Metabolism | |
| Biological Activity | Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously. Logani_MK et al. Sevanian_A et al. Fujimoto_K . It reacts with DNA in the presence of Fe ions and ascorbic acid Fujimoto_K et al.. |
| Genetic Information | |
| Note | Isomerization of hydroperoxides: Positional isomers at 9, 10, 12, 13, 15, and 16 and their geometric isomers of cis, cis, trans- or cis, trans, trans are formed. The proportion of 9-, 16- isomers is higher than that of 12-, 13- isomers. |
| Spectral Information | |
| Mass Spectra | EI-MS(Me-ester; after reduction and hydrogenation) Chan_HWS : m/e=201[O=CH(CH2)8C(=OH)OCH3]; 172[CH2(CH2)7C(=O)OCH3];169[O=CH(CH2)8C=O]; GC-EI-MS (Me-ester; after reduction, TMS) TeraoJet al.: m/e=271[SMTO=CH-CH=CH(CH2)6COOCH3], GC-EI-MS(Me-ester;after reduction, hydrogenation) |
| UV Spectra | |
| IR Spectra | |
| NMR Spectra | |
| Other Spectra | |
| Chromatograms | |
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